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Janice Kaspersen Janice Kaspersen Stormwater Editor

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SW Editor's Blog

February 17th, 2009 5:47am PST

How Dangerous Is Chitosan, Really? Do We Need Certification?

Posted By Janice Kaspersen 2 Comments

At the International Erosion Control Association’s conference last week in Reno last week, a group of people got together to discuss EPA’s proposed Effluent Limitations Guidelines. Representing both the regulators and the regulated, the group included Jesse Pritts of USEPA, Eric Berntsen of the California State Water Resources Control Board, Cory Taylor of Beazer Homes USA, and Robert Patterson of Pulte Home Corporation. I summarized some of their comments, particularly those on the costs of implementing the proposed guidelines, here. But one point that came up deserves from further attention from stormwater managers.

For some construction sites in some areas of the country, the guidelines propose a numeric effluent limitation of 13 nephelometric turbidity units (NTUs). To achieve this, EPA says, it will probably be necessary to use an advanced treatment system, such as chitosan-enhanced filtration treatment, polymer clarification, or electrocoagulation. During last week’s discussion, Robert Patterson questioned what sort of certification would be in place, if any, for people operating such systems, suggesting that concentrated chitosan released to a water body would be toxic and would result in a fish kill. Some states have banned other types of flocculants, and chitosan was therefore the main one he considered in his analysis of the costs of implementing the guidelines.

This is the passage from EPA’s proposal that addresses the potential risk:

 “It has been suggested that, while operating active treatmentsystems that use polymers to reduce the turbidity of stormwater,construction site dischargers may overuse polymers and, in doing so,introduce toxicity or cause other adverse effects. EPA believes toxiceffects from discharges treated to meet a turbidity limit should not beoccurring and such events would be indicative of a poorly operatedtreatment system. Polymers are widely used at a variety of wastewatertreatment systems and facilities throughout the country, and EPA is notaware of any studies indicating that polymer addition to treatstormwater from construction sites using ATS has been found to pose asignificant risk to water quality at those facilities. There are ampleregulatory (i.e., enforcement actions) and financial (e.g., chemicalcosts) disincentives for dischargers to willfully overuse polymers intheir treatment systems. In addition, vendors have indicated thatdosages of polymers are carefully metered in ATS systems. Upon closerreview of the matter, it appears that this concern has been raised dueto anecdotal suggestions, rather than documented evidence of actualdischarge events causing toxic effects. To date, EPA has not identifiedany documented cases where the use of a polymer to treat C&D stormwater discharges caused an adverse effect in the receiving waters.”

(You can read the entire proposal as it appeared in the Federal Register here).

The counterargument goes something like this: As more and more sites than ever before begin to use advanced treatment systems, inevitably some systems will be handled by poorly trained operators, and accidents will be more likely; just because EPA is not aware of significant risks in the past doesn’t mean there won’t be more and greater problems in the future.

What is your experience with such systems, and what sort of safeguards do you think should be in place if the guidelines are approved? Do we need more detailed toxicity studies? Guidelines for operators of advanced treatment systems? An actual certification program?

 

What Do You Think?

Post a Comment

eshradar

March 5th, 2009 9:13 AM PT

Good points! Also, generally speaking POTWs have a consistent inflow of water. Construction sites do not, since it is storm dependent. I may be incorrect, but I thought chitosan was a flocculant (like alum), but not a polymer. The polymers I am familiar with are not toxic, when used correctly and even then have a wide margin of error. Chitosan and alum are not so generous. For EPA to assume that all such ASTs are equal is now wise. We didn't know what the impact of draining the Everglades would be, or the impact of unregulated fertilizer runoff until many years later and now we are spending Billions to fix our short sighted errors. Let's learn from the past and be more cautious before blanket suggesting systems.

alansearcy

March 4th, 2009 8:43 AM PT

It is a mistake on the part of the EPA to equate the intricate workings, staffing and technology utilized in a POTW with a mobile ATS system on a construction site. In regulator land there appears to be an assumption that since they both can be permitted in the same way they must therefore behave in exactly the same way. POTW's are supported by their rate payers by monthly billing. ATS's are not. POTW's are stationary, permanent facilities. ATS's are not. POTW's are multi-billion dollar installations. ATS's are not. POTW's are staffed 24hrs per day and are constantly being upgraded. ATS's are not. Flow is carefully regulated at POTW's to maintain the proper ratios and chemical balances of added materials. ATS's are not. The argument that since no degradation of waters by flocculants has been reported to date, again assumes that the current users of flocculants are the same users that will operate ATS's. They are not. I have never seen a report of a chimpanzee shooting anyone in the U.S. That said, I won't be giving a monkey a loaded gun anytime soon.

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